Thrust is the force that propels a rocket or spacecraft and is measured in pounds, kilograms or Newtons. Physically speaking, it is the result of pressure which is exerted on the wall of the combustion chamber.

Figure 1.1 shows a combustion chamber with an opening, the nozzle, through which gas can escape. The pressure distribution within the chamber is asymmetric; that is, inside the chamber the pressure varies little, but near the nozzle it decreases somewhat. The force due to gas pressure on the bottom of the chamber is not compensated for from the outside. The resultant force F due to the internal and external pressure difference, the thrust, is opposite to the direction of the gas jet. It pushes the chamber upwards.

To create high speed exhaust gases, the necessary high temperatures and pressures of combustion are obtained by using a very energetic fuel and by having the molecular weight of the exhaust gases as low as possible. It is also necessary to reduce the pressure of the gas as much as possible inside the nozzle by creating a large section ratio. The section ratio, or expansion ratio, is defined as the area of the exit A_e divided by the area of the throat A_t.

The thrust F is the resultant of the forces due to the pressures exerted on the inner and outer walls by the combustion gases and the surrounding atmosphere, taking the boundary between the inner and outer surfaces as the cross section of the exit of the nozzle. As we shall see in the next section, applying the principle of the conservation of momentum gives

where q is the rate of the ejected mass flow, P_a the pressure of the ambient atmosphere, P_e the pressure of the exhaust gases and V_e their ejection speed. Thrust is specified either at sea level or in a vacuum.

The linear momentum (p), or simply momentum, of a particle is the product of its mass and its velocity. That is,

Newton expressed his second law of motion in terms of momentum, which can be stated as "the resultant of the forces acting on a particle is equal to the rate of change of the linear momentum of the particle". In symbolic form this becomes

which is equivalent to the expression F=ma.

If we have a system of particles, the total momentum P of the system is the sum of the momenta of the individual particles. When the resultant external force acting on a system is zero, the total linear momentum of the system remains constant. This is called the principle of conservation of linear momentum. Let's now see how this principle is applied to rocket mechanics.

Consider a rocket drifting in gravity free space. The rocket's engine is fired for time t and, during this period, ejects gases at a constant rate and at a constant speed relative to the rocket (exhaust velocity). Assume there are no external forces, such as gravity or air resistance.

Figure 1.2(a) shows the situation at time t. The rocket and fuel have a total mass M and the combination is moving with velocity v as seen from a particular frame of reference. At a time t later the configuration has changed to that shown in Figure 1.2(b). A mass M has been ejected from the rocket and is moving with velocity u as seen by the observer. The rocket is reduced to mass M-M and the velocity v of the rocket is changed to v+v.

Because there are no external forces, dP/dt=0. We can write, for the time interval t

where P₂ is the final system momentum, Figure 1.2(b), and P₁ is the initial system momentum, Figure 1.2(a). We write

If we let t approach zero, v/t approaches dv/dt, the acceleration of the body. The quantity M is the mass ejected in t; this leads to a decrease in the mass M of the original body. Since dM/dt, the change in mass of the body with time, is negative in this case, in the limit the quantity M/t is replaced by -dM/dt. The quantity u-(v+v) is V_rel, the relative velocity of the ejected mass with respect to the rocket. With these changes, equation (1.4) can be written as

The right-hand term depends on the characteristics of the rocket and, like the left-hand term, has the dimensions of a force. This force is called the thrust, and is the reaction force exerted on the rocket by the mass that leaves it. The rocket designer can make the thrust as large as possible by designing the rocket to eject mass as rapidly as possible (dM/dt large) and with the highest possible relative speed (V_rel large).

In rocketry, the basic thrust equation is written as

where q is the rate of the ejected mass flow, V_e is the exhaust gas ejection speed, P_e is the pressure of the exhaust gases at the nozzle exit, P_a is the pressure of the ambient atmosphere, and A_e is the area of the nozzle exit. The product qV_e, which we derived above (V_rel × dM/dt), is called the momentum, or velocity, thrust. The product (P_e-P_a)A_e, called the pressure thrust, is the result of unbalanced pressure forces at the nozzle exit. As we shall see latter, maximum thrust occurs when P_e=P_a.

In the preceding section we saw that Newton's second law may be expressed in the form

Multiplying both sides by dt and integrating from a time t₁ to a time t₂, we write

The integral is a vector known as the linear impulse, or simply the impulse, of the force F during the time interval considered. The equation expresses that, when a particle is acted upon by a force F during a given time interval, the final momentum p₂ of the particle may be obtained by adding its initial momentum p₁ and the impulse of the force F during the interval of time.

When several forces act on a particle, the impulse of each of the forces must be considered. When a problem involves a system of particles, we may add vectorially the momenta of all the particles and the impulses of all the forces involved. When can then write

For a time interval t, we may write equation (1.10) in the form

Let us now see how we can apply the principle of impulse and momentum to rocket mechanics.

Consider a rocket of initial mass M which it launched vertically at time t=0. The fuel is consumed at a constant rate q and is expelled at a constant speed V_e relative to the rocket. At time t, the mass of the rocket shell and remaining fuel is M-qt, and the velocity is v. During the time interval t, a mass of fuel qt is expelled. Denoting by u the absolute velocity of the expelled fuel, we apply the principle of impulse and momentum between time t and time t+t. Please note, this derivation neglects the effect of air resistance.

We write

We divide through by t and replace u-(v+v) with V_e, the velocity of the expelled mass relative to the rocket. As t approaches zero, we obtain

Separating variables and integrating from t=0, v=0 to t=t, v=v, we obtain

which equals

The term -gt in equation (1.15) is the result of Earth's gravity pulling on the rocket. For a rocket drifting in space, -gt is not applicable and can be omitted. Furthermore, it is more appropriate to express the resulting velocity as a change in velocity, or V. Equation (1.15) thus becomes

The combustion process involves the oxidation of constituents in the fuel that are capable of being oxidized, and can therefore be represented by a chemical equation. During a combustion process the mass of each element remains the same. Consider the reaction of methane with oxygen

This equation states that one mole of methane reacts with two moles of oxygen to form one mole of carbon dioxide and two moles of water. This also means that 16 g of methane react with 64 g of oxygen to form 44 g of carbon dioxide and 36 g of water. All the initial substances that undergo the combustion process are called the reactants, and the substances that result from the combustion process are called the products.

The above combustion reaction is an example of a stoichiometric mixture, that is, there is just enough oxygen present to chemically react with all the fuel. The highest flame temperature is achieved under these conditions, however it is often desirable to operate a rocket engine at a "fuel-rich" mixture ratio. Mixture ratio is defined as the mass flow of oxidizer divided by the mass flow of fuel.

Consider the following reaction of kerosene⁽¹⁾ with oxygen,

Given the molecular weight of C₁₂H₂₆ is 170 and that of O₂ is 32, we have a mixture ratio of

which is typical of many rocket engines using kerosene, or RP-1, fuel.

The optimum mixture ratio is typically that which will deliver the highest engine performance (measured by specific impulse), however in some situations a different O/F ratio results in a better overall system. For a volume-constrained vehicle with a low-density fuel such as liquid hydrogen, significant reductions in vehicle size can be achieved by shifting to a higher O/F ratio. In that case, the losses in performance are more than compensated for by the reduced fuel tankage requirement. Also consider the example of bipropellant systems using NTO/MMH, where a mixture ratio of 1.67 results in fuel and oxidizer tanks of equal size. Equal sizing simplifies tank manufacturing, system packaging, and integration.

As we have seen previously, impulse thrust is equal to the product of the propellant mass flow rate and the exhaust gas ejection speed. The ideal exhaust velocity is given by

where k is the specific heat ratio, R* is the universal gas constant (8,314.4621 J/kmol-K in SI units, or 49,720 ft-lb/(slug-mol)-^oR in U.S. units), T_c is the combustion temperature, M is the average molecular weight of the exhaust gases, P_c is the combustion chamber pressure, and P_e is the pressure at the nozzle exit.

Specific heat ratio⁽²⁾ varies depending on the composition and temperature of the exhaust gases, but it is usually about 1.2. The thermodynamics involved in calculating combustion temperatures are quite complicated, however, flame temperatures generally range from about 2,500 to 3,600 ^oC (4,500-6,500 ^oF). Chamber pressures can range from about about 7 to 250 atmospheres. P_e should be equal to the ambient pressure at which the engine will operate, more on this later.

From equation (1.22) we see that high chamber temperature and pressure, and low exhaust gas molecular weight results in high ejection velocity, thus high thrust. Based on this criterion, we can see why liquid hydrogen is very desirable as a rocket fuel.

The specific impulse of a rocket, I_sp, is the ratio of the thrust to the flow rate of the weight ejected, that is

where F is thrust, q is the rate of mass flow, and g_o is standard gravity (9.80665 m/s²).

Specific impulse is expressed in seconds. When the thrust and the flow rate remain constant throughout the burning of the propellant, the specific impulse is the time for which the rocket engine provides a thrust equal to the weight of the propellant consumed.

For a given engine, the specific impulse has different values on the ground and in the vacuum of space because the ambient pressure is involved in the expression for the thrust. It is therefore important to state whether specific impulse is the value at sea level or in a vacuum.

There are a number of losses within a rocket engine, the main ones being related to the inefficiency of the chemical reaction (combustion) process, losses due to the nozzle, and losses due to the pumps. Overall, the losses affect the efficiency of the specific impulse. This is the ratio of the real specific impulse (at sea level, or in a vacuum) and the theoretical specific impulse obtained with an ideal nozzle from gases coming from a complete chemical reaction. Calculated values of specific impulse are several percent higher than those attained in practice.

A typical rocket engine consists of the nozzle, the combustion chamber, and the injector, as shown in Figure 1.4. The combustion chamber is where the burning of propellants takes place at high pressure. The chamber must be strong enough to contain the high pressure generated by, and the high temperature resulting from, the combustion process. Because of the high temperature and heat transfer, the chamber and nozzle are usually cooled. The chamber must also be of sufficient length to ensure complete combustion before the gases enter the nozzle.

Nozzle

The function of the nozzle is to convert the chemical-thermal energy generated in the combustion chamber into kinetic energy. The nozzle converts the slow moving, high pressure, high temperature gas in the combustion chamber into high velocity gas of lower pressure and temperature. Since thrust is the product of mass and velocity, a very high gas velocity is desirable. Nozzles consist of a convergent and divergent section. The minimum flow area between the convergent and divergent section is called the nozzle throat. The flow area at the end of the divergent section is called the nozzle exit area. The nozzle is usually made long enough (or the exit area is great enough) such that the pressure in the combustion chamber is reduced at the nozzle exit to the pressure existing outside the nozzle. It is under this condition, P_e=P_a where P_e is the pressure at the nozzle exit and P_a is the outside ambient pressure, that thrust is maximum and the nozzle is said to be adapted, also called optimum or correct expansion. When P_e is greater than P_a, the nozzle is under-extended. When the opposite is true, it is over-extended.

We see therefore, a nozzle is designed for the altitude at which it has to operate. At the Earth's surface, at the atmospheric pressure of sea level (0.1 MPa or 14.7 psi), the discharge of the exhaust gases is limited by the separation of the jet from the nozzle wall. In the cosmic vacuum, this physical limitation does not exist. Therefore, there have to be two different types of engines and nozzles, those which propel the first stage of the launch vehicle through the atmosphere, and those which propel subsequent stages or control the orientation of the spacecraft in the vacuum of space.

The nozzle throat area, A_t, can be found if the total propellant flow rate is known and the propellants and operating conditions have been selected. Assuming perfect gas law theory, we have

where q is the propellant mass flow rate, P_t is the gas pressure at the nozzle throat, T_t is the gas temperature at the nozzle throat, R* is the universal gas constant, and k is the specific heat ratio. P_t and T_t are given by

where P_c is the combustion chamber pressure and T_c is the combustion chamber flame temperature.

Liquid bipropellant rocket engines can be categorized according to their power cycles, that is, how power is derived to feed propellants to the main combustion chamber. Described below are some of the more common types.

Gas-generator cycle: The gas-generator cycle, also called open cycle, taps off a small amount of fuel and oxidizer from the main flow (typically 2 to 7 percent) to feed a burner called a gas generator. The hot gas from this generator passes through a turbine to generate power for the pumps that send propellants to the combustion chamber. The hot gas is then either dumped overboard or sent into the main nozzle downstream. Increasing the flow of propellants into the gas generator increases the speed of the turbine, which increases the flow of propellants into the main combustion chamber, and hence, the amount of thrust produced. The gas generator must burn propellants at a less-than-optimal mixture ratio to keep the temperature low for the turbine blades. Thus, the cycle is appropriate for moderate power requirements but not high-power systems, which would have to divert a large portion of the main flow to the less efficient gas-generator flow.

As in most rocket engines, some of the propellant in a gas generator cycle is used to cool the nozzle and combustion chamber, increasing efficiency and allowing higher engine temperature.

Staged combustion cycle: In a staged combustion cycle, also called closed cycle, the propellants are burned in stages. Like the gas-generator cycle, this cycle also has a burner, called a preburner, to generate gas for a turbine. The preburner taps off and burns a small amount of one propellant and a large amount of the other, producing an oxidizer-rich or fuel-rich hot gas mixture that is mostly unburned vaporized propellant. This hot gas is then passed through the turbine, injected into the main chamber, and burned again with the remaining propellants. The advantage over the gas-generator cycle is that all of the propellants are burned at the optimal mixture ratio in the main chamber and no flow is dumped overboard. The staged combustion cycle is often used for high-power applications. The higher the chamber pressure, the smaller and lighter the engine can be to produce the same thrust. Development cost for this cycle is higher because the high pressures complicate the development process. Further disadvantages are harsh turbine conditions, high temperature piping required to carry hot gases, and a very complicated feedback and control design.

Staged combustion was invented by Soviet engineers and first appeared in 1960. In the West, the first laboratory staged combustion test engine was built in Germany in 1963.

Expander cycle: The expander cycle is similar to the staged combustion cycle but has no preburner. Heat in the cooling jacket of the main combustion chamber serves to vaporize the fuel. The fuel vapor is then passed through the turbine and injected into the main chamber to burn with the oxidizer. This cycle works with fuels such as hydrogen or methane, which have a low boiling point and can be vaporized easily. As with the staged combustion cycle, all of the propellants are burned at the optimal mixture ratio in the main chamber, and typically no flow is dumped overboard; however, the heat transfer to the fuel limits the power available to the turbine, making this cycle appropriate for small to midsize engines. A variation of the system is the open, or bleed, expander cycle, which uses only a portion of the fuel to drive the turbine. In this variation, the turbine exhaust is dumped overboard to ambient pressure to increase the turbine pressure ratio and power output. This can achieve higher chamber pressures than the closed expander cycle although at lower efficiency because of the overboard flow.

Pressure-fed cycle: The simplest system, the pressure-fed cycle, does not have pumps or turbines but instead relies on tank pressure to feed the propellants into the main chamber. In practice, the cycle is limited to relatively low chamber pressures because higher pressures make the vehicle tanks too heavy. The cycle can be reliable, given its reduced part count and complexity compared with other systems.

The heat created during combustion in a rocket engine is contained within the exhaust gases. Most of this heat is expelled along with the gas that contains it; however, heat is transferred to the thrust chamber walls in quantities sufficient to require attention.

Thrust chamber designs are generally categorized or identified by the hot gas wall cooling method or the configuration of the coolant passages, where the coolant pressure inside may be as high as 500 atmospheres. The high combustion temperatures (2,500 to 3,600^o K) and the high heat transfer rates (up to 16 kJ/cm²-s) encountered in a combustion chamber present a formidable challenge to the designer. To meet this challenge, several chamber cooling techniques have been utilized successfully. Selection of the optimum cooling method for a thrust chamber depends on many considerations, such as type of propellant, chamber pressure, available coolant pressure, combustion chamber configuration, and combustion chamber material.

Regenerative cooling is the most widely used method of cooling a thrust chamber and is accomplished by flowing high-velocity coolant over the back side of the chamber hot gas wall to convectively cool the hot gas liner. The coolant with the heat input from cooling the liner is then discharged into the injector and utilized as a propellant.

Earlier thrust chamber designs, such as the V-2 and Redstone, had low chamber pressure, low heat flux and low coolant pressure requirements, which could be satisfied by a simplified "double wall chamber" design with regenerative and film cooling. For subsequent rocket engine applications, however, chamber pressures were increased and the cooling requirements became more difficult to satisfy. It became necessary to design new coolant configurations that were more efficient structurally and had improved heat transfer characteristics.

This led to the design of "tubular wall" thrust chambers, by far the most widely used design approach for the vast majority of large rocket engine applications. These chamber designs have been successfully used for the Thor, Jupiter, Atlas, H-1, J-2, F-1, RS-27 and several other Air Force and NASA rocket engine applications. The primary advantage of the design is its light weight and the large experience base that has accrued. But as chamber pressures and hot gas wall heat fluxes have continued to increase (>100 atm), still more effective methods have been needed.

One solution has been "channel wall" thrust chambers, so named because the hot gas wall cooling is accomplished by flowing coolant through rectangular channels, which are machined or formed into a hot gas liner fabricated from a high-conductivity material, such as copper or a copper alloy. A prime example of a channel wall combustion chamber is the SSME, which operates at 204 atmospheres nominal chamber pressure at 3,600 K for a duration of 520 seconds. Heat transfer and structural characteristics are excellent.

In addition to the regeneratively cooled designs mentioned above, other thrust chamber designs have been fabricated for rocket engines using dump cooling, film cooling, transpiration cooling, ablative liners and radiation cooling. Although regeneratively cooled combustion chambers have proven to be the best approach for cooling large liquid rocket engines, other methods of cooling have also been successfully used for cooling thrust chamber assemblies. Examples include:

Dump cooling, which is similar to regenerative cooling because the coolant flows through small passages over the back side of the thrust chamber wall. The difference, however, is that after cooling the thrust chamber, the coolant is discharged overboard through openings at the aft end of the divergent nozzle. This method has limited application because of the performance loss resulting from dumping the coolant overboard. To date, dump cooling has not been used in an actual application.

Film cooling provides protection from excessive heat by introducing a thin film of coolant or propellant through orifices around the injector periphery or through manifolded orifices in the chamber wall near the injector or chamber throat region. This method is typically used in high heat flux regions and in combination with regenerative cooling.

Transpiration cooling provides coolant (either gaseous or liquid propellant) through a porous chamber wall at a rate sufficient to maintain the chamber hot gas wall to the desired temperature. The technique is really a special case of film cooling.

With ablative cooling, combustion gas-side wall material is sacrificed by melting, vaporization and chemical changes to dissipate heat. As a result, relatively cool gases flow over the wall surface, thus lowering the boundary-layer temperature and assisting the cooling process.

With radiation cooling, heat is radiated from the outer surface of the combustion chamber or nozzle extension wall. Radiation cooling is typically used for small thrust chambers with a high-temperature wall material (refractory) and in low-heat flux regions, such as a nozzle extension.

Solid rockets motors store propellants in solid form. The fuel is typically powdered aluminum and the oxidizer is ammonium perchlorate. A synthetic rubber binder such as polybutadiene holds the fuel and oxidizer powders together. Though lower performing than liquid propellant rockets, the operational simplicity of a solid rocket motor often makes it the propulsion system of choice.

Solid Fuel Geometry

A solid fuel's geometry determines the area and contours of its exposed surfaces, and thus its burn pattern. There are two main types of solid fuel blocks used in the space industry. These are cylindrical blocks, with combustion at a front, or surface, and cylindrical blocks with internal combustion. In the first case, the front of the flame travels in layers from the nozzle end of the block towards the top of the casing. This so-called end burner produces constant thrust throughout the burn. In the second, more usual case, the combustion surface develops along the length of a central channel. Sometimes the channel has a star shaped, or other, geometry to moderate the growth of this surface.

The shape of the fuel block for a rocket is chosen for the particular type of mission it will perform. Since the combustion of the block progresses from its free surface, as this surface grows, geometrical considerations determine whether the thrust increases, decreases or stays constant.

Fuel blocks with a cylindrical channel (1) develop their thrust progressively. Those with a channel and also a central cylinder of fuel (2) produce a relatively constant thrust, which reduces to zero very quickly when the fuel is used up. The five pointed star profile (3) develops a relatively constant thrust which decreases slowly to zero as the last of the fuel is consumed. The 'cruciform' profile (4) produces progressively less thrust. Fuel in a block with a 'double anchor' profile (5) produces a decreasing thrust which drops off quickly near the end of the burn. The 'cog' profile (6) produces a strong inital thrust, followed by an almost constant lower thrust.

Burn Rate

The burning surface of a rocket propellant grain recedes in a direction perpendicular to this burning surface. The rate of regression, typically measured in millimeters per second (or inches per second), is termed burn rate. This rate can differ significantly for different propellants, or for one particular propellant, depending on various operating conditions as well as formulation. Knowing quantitatively the burning rate of a propellant, and how it changes under various conditions, is of fundamental importance in the successful design of a solid rocket motor.

Propellant burning rate is influenced by certain factors, the most significant being: combustion chamber pressure, initial temperature of the propellant grain, velocity of the combustion gases flowing parallel to the burning surface, local static pressure, and motor acceleration and spin. These factors are discussed below.

• Burn rate is profoundly affected by chamber pressure. The usual representation of the pressure dependence on burn rate is the Saint-Robert's Law,

  

  where r is the burn rate, a is the burn rate coefficient, n is the pressure exponent, and P_c is the combustion chamber pressure. The values of a and n are determined empirically for a particular propellant formulation and cannot be theoretically predicted. It is important to realize that a single set of a, n values are typically valid over a distinct pressure range. More than one set may be necessary to accurately represent the full pressure regime of interest.

  Example a, n values are 0.0445289* (pressure in pascals, burn rate in mm/s) and 0.35 respectively for the Space Shuttle SRBs, which gives a burn rate of 9.34 mm/s at the average chamber pressure of 4.3 MPa.

  * NASA publications gives a burn rate coefficient of 0.0386625 (pressure in PSI, burn rate in inch/s).

• Temperature affects the rate of chemical reactions and thus the initial temperature of the propellant grain influences burning rate. If a particular propellant shows significant sensitivity to initial grain temperature, operation at temperature extremes will affect the time-thrust profile of the motor. This is a factor to consider for winter launches, for example, when the grain temperature may be lower than "normal" launch conditions.
• For most propellants, certain levels of local combustion gas velocity (or mass flux) flowing parallel to the burning surface leads to an increased burning rate. This "augmentation" of burn rate is referred to as erosive burning, with the extent varying with propellant type and chamber pressure. For many propellants, a threshold flow velocity exists. Below this flow level, either no augmentation occurs, or a decrease in burn rate is experienced (negative erosive burning).

  The effects of erosive burning can be minimized by designing the motor with a sufficiently large port-to-throat area ratio (A_port/A_t). The port area is the cross-section area of the flow channel in a motor. For a hollow-cylindrical grain, this is the cross-section area of the core. As a rule of thumb, the ratio should be a minimum of 2 for a grain L/D ratio of 6. A greater A_port/A_t ratio should be used for grains with larger L/D ratios.

• In an operating rocket motor, there is a pressure drop along the axis of the combustion chamber, a drop that is physically necessary to accelerate the increasing mass flow of combustion products toward the nozzle. The static pressure is greatest where gas flow is zero, that is, at the front of the motor. Since burn rate is dependant upon the local pressure, the rate should be greatest at this location. However, this effect is relatively minor and is usually offset by the counter-effect of erosive burning.
• Burning rate is enhanced by acceleration of the motor. Whether the acceleration is a result of longitudinal force (e.g. thrust) or spin, burning surfaces that form an angle of about 60-90^o with the acceleration vector are prone to increased burn rate.

It is sometimes desirable to modify the burning rate such that it is more suitable to a certain grain configuration. For example, if one wished to design an end burner grain, which has a relatively small burning area, it is necessary to have a fast burning propellant. In other circumstances, a reduced burning rate may be sought after. For example, a motor may have a large L/D ratio to generate sufficiently high thrust, or it may be necessary for a particular design to restrict the diameter of the motor. The web would be consequently thin, resulting in short burn duration. Reducing the burning rate would be beneficial.

There are a number of ways of modifying the burning rate: decrease the oxidizer particle size, increase or reduce the percentage of oxidizer, adding a burn rate catalyst or suppressant, and operate the motor at a lower or higher chamber pressure. These factors are discussed below.

• The effect of the oxidizer particle size on burn rate seems to be influenced by the type of oxidizer. Propellants that use ammonium perchlorate (AP) as the oxidizer have a burn rate that is significantly affected by AP particle size. This most likely results from the decomposition of AP being the rate-determining step in the combustion process.
• The burn rate of most propellants is strongly influenced by the oxidizer/fuel ratio. Unfortunately, modifying the burn rate by this means is quite restrictive, as the performance of the propellant, as well as mechanical properties, are also greatly affected by the O/F ratio.
• Certainly the best and most effective means of increasing the burn rate is the addition of a catalyst to the propellant mixture. A catalyst is a chemical compound that is added in small quantities for the sole purpose of tailoring the burning rate. A burn rate suppressant is an additive that has the opposite effect to that of a catalyst – it is used to decrease the burn rate.
• For a propellant that follows the Saint-Robert's burn rate law, designing a rocket motor to operate at a lower chamber pressure will provide for a lower burning rate. Due to the nonlinearity of the pressure-burn rate relationship, it may be necessary to significantly reduce the operating pressure to get the desired burning rate. The obvious drawback is reduced motor performance, as specific impulse similarly decays with reducing chamber pressure.

Product Generation Rate

The rate at which combustion products are generated is expressed in terms of the regression speed of the grain. The product generation rate integrated over the port surface area is

where q is the combustion product generation rate at the propellant surface, _p is the solid propellant density, A_b is the area of the burning surface, and r is the propellant burn rate.

By far the most widely used type of propulsion for spacecraft attitude and velocity control is monopropellant hydrazine. Its excellent handling characteristics, relative stability under normal storage conditions, and clean decomposition products have made it the standard. The general sequence of operations in a hydrazine thruster is:

• When the attitude control system signals for thruster operation, an electric solenoid valve opens allowing hydrazine to flow. The action may be pulsed (as short as 5 ms) or long duration (steady state).
• The pressure in the propellant tank forces liquid hydrazine into the injector. It enters as a spray into the thrust chamber and contacts the catalyst beds.
• The catalyst bed consists of alumina pellets impregnated with iridium. Incoming hydrazine heats to its vaporizing point by contact with the catalyst bed and with the hot gases leaving the catalyst particles. The temperature of the hydrazine rises to a point where the rate of its decomposition becomes so high that the chemical reactions are self-sustaining.
• By controlling the flow variables and the geometry of the catalyst chamber, a designer can tailor the proportion of chemical products, the exhaust temperature, the molecular weight, and thus the enthalpy for a given application. For a thruster application where specific impulse is paramount, the designer attempts to provide 30-40% ammonia dissociation, which is about the lowest percentage that can be maintained reliably. For gas-generator application, where lower temperature gases are usually desired, the designer provides for higher levels of ammonia dissociation.
• Finally, in a space thruster, the hydrazine decomposition products leave the catalyst bed and exit from the chamber through a high expansion ratio exhaust nozzle to produce thrust.

Monopropellant hydrazine thrusters typically produce a specific impulse of about 230 to 240 seconds.

Other suitable propellants for catalytic decomposition engines are hydrogen peroxide and nitrous oxide, however the performance is considerably lower than that obtained with hydrazine - specific impulse of about 150 s with H₂O₂ and about 170 s with N₂O.

Monopropellant systems have successfully provided orbit maintenance and attitude control functions, but lack the performance to provide weight-efficient large V maneuvers required for orbit insertion. Bipropellant systems are attractive because they can provide all three functions with one higher performance system, but they are more complex than the common solid rocket and monopropellant combined systems. A third alternative are dual mode systems. These systems are hybrid designs that use hydrazine both as a fuel for high performance bipropellant engines and as a monopropellant with conventional low-thrust catalytic thrusters. The hydrazine is fed to both the bipropellant engines and the monopropellant thrusters from a common fuel tank.

Cold gas propulsion is just a controlled, pressurized gas source and a nozzle. It represents the simplest form of rocket engine. Cold gas has many applications where simplicity and/or the need to avoid hot gases are more important than high performance. The Manned Maneuvering Unit used by astronauts is an example of such a system.

Multistage rockets allow improved payload capability for vehicles with a high V requirement such as launch vehicles or interplanetary spacecraft. In a multistage rocket, propellant is stored in smaller, separate tanks rather than a larger single tank as in a single-stage rocket. Since each tank is discarded when empty, energy is not expended to accelerate the empty tanks, so a higher total V is obtained. Alternatively, a larger payload mass can be accelerated to the same total V. For convenience, the separate tanks are usually bundled with their own engines, with each discardable unit called a stage.

Multistage rocket performance is described by the same rocket equation as single-stage rockets, but must be determined on a stage-by-stage basis. The velocity increment, V_i, for each stage is calculated as before,

where m_oi represents the total vehicle mass when stage i is ignited, and m_fi is the total vehicle mass when stage i is burned out but not yet discarded. It is important to realize that the payload mass for any stage consists of the mass of all subsequent stages plus the ultimate payload itself. The velocity increment for the vehicle is then the sum of those for the individual stages where n is the total number of stages.